You probably have heard that the most popular HFCrefrigerants being widely used today are global warming gasses. In fact, some popularHFC refrigerants have higher GWPs than the CFCs and HCFCs they replaced. Arefrigerant’s Global warming potential (GWP) compares it to CO
2, theglobal warming gas produced by burning hydrocarbons. A GWP of 1 indicates thata gas has the same effect on global warming as CO
2. The retiredpopular air conditioning refrigerant, HCFC 22, has a GWP of 1760. HFC 410A that is now widely used in airconditioning applications has a GWP of 1924. It is actually worse! MeanwhileHFC 404A, popular in refrigeration applications, has a GWP of 3943. HFC 134a ispopular in domestic refrigerators, commercial refrigeration, and car airconditioning has a GWP of 1300. These high GWP numbers have made HFCrefrigerants the target of regulatory efforts to limit their use and replacethem with more environmentally friendly refrigerants. Europe has movedaggressively, passing their F-Gas regulations. The ultimate objective of theF-Gas Regulations is to cut the availability of HFCs by 79% between 2015 and2030. There will also be a servicing ban on HFCs with a GWP >2500 forcertain sectors.
Here is a link to a quick overview of the F-Gas regulations byMitsubishi.
While the US has not moved nearly as aggressively, therehave been attempts by the EPA to regulate refrigerants based on their GWP. Worldwideregulatory restrictions on current HFC refrigerants has spurred development oflower GWP refrigerants. Manufacturers in the HVACR industry have been activelydeveloping lower GWP alternative refrigerants.
HYDROCARBONS
Propane (R290), Isobutane (R600a), and R441A all have verylow GWPs of (3, 3,0). They are all non-ozone depleting and non-toxic. Theirlimitation is their flammability – they are all highly flammable. In the USthey are approved only for systems with a charge of 150 grams (5 ounces) orless. In Europe hydrocarbon refrigerants have been used in refrigerators andfreezers for years. These refrigerants are now common in residential refrigeratorand small commercial refrigeration units in the US. While highly flammablerefrigerants are likely to remain a factor in small commercial refrigerationsystems, it is unlikely that these refrigerants will be used in larger systemsin the US due to our aversion for being sued and the large number of lawyers inthe US.
CO2 R744
It is interesting that the main global warming culprit, CO
2,is also a refrigerant with a very low GWP of 1. It does not deplete the ozone,it is non-toxic, non-flammable, and cheap. What’s not to like? Unfortunately,CO
2 has a critical temperature of 88°F. It cannot condense above88°F. This means that CO
2 systems are not “normal” systems. CO
2systems must either be transcritical or cascade systems. Transcritical systems operateat very high pressures of 1200 – 1500 psig on the high side. Cascade systemsuse the evaporator of one system to cool the condenser of another system.Either way, CO
2 systems are more complicated and expensive than traditionalsystem. One place that CO
2 has taken root is in large scalecommercial refrigeration rack systems. Complexity in large rack refrigeration systemsis normal and the extra cost of the transcritcial components is offset by thesavings in refrigerant cost. However, in smaller scale systems the cost of a CO
2system is prohibitive. For a quick explanation of a transcritical system checkout
https://www.achrnews.com/articles/94092-co2-as-refrigerant-the-transcritical-cycle
AMMONIA R717
Ammonia refrigeration has been around since the earliestdays of refrigeration. Ammonia has always been used in large scale foodcommercial refrigeration and freezing for food processing because of itsefficiency and low cost. Unfortunately, ammonia (R-717) has many applicationchallenges. It is toxic, somewhat flammable, and cannot be used with somemetals, such as brass or copper. It will continue to be a mainstay ofcommercial food processing, but I doubt you will see it expand into othermarket segments.
LOWER GWP HFCs
There are some HFC refrigerants that have a GWP in thehundreds instead of the thousands. While these refrigerants are probably notlong-term solutions, they can provide a way to drastically reduce the GWPfootprint of a system without a drastic change in technology or design.
R 32
HFC R-32 has been adopted by many manufacturers in airconditioning systems sold outside of the United States. R-32 is an HFC with alower GWP of 667. That is still not really low compared to CO2 (GWP 1) orammonia (GWP 0), but it is considerably lower than R404A, R410A, or R134a. HFC32has the advantage of being a relatively “normal” refrigerant, making designingsystems to use it less challenging than say, CO
2. However, R-32 isflammable. While not as flammable as propane, it does burn. That precludes itsuse in most applications in the US, at least right now. The building and safetycodes in the US do not allow a flammable refrigerant in systems where the airin the building flows directly over the evaporator. These codes make nodistinction between A2L and A3 refrigerants. To them, flammable is flammable. Manufacturers and code officials in the US areworking to determine what new requirements an A2L refrigerant system shouldhave to make it safe for use. The one place you will find R32 in the US is inwindow air conditioners. The EPA allows use of R32 in limited quantities inwindow units.
Here is a link for more information on R32.
R466A (Solstice N41)
Honeywell has developed an A1 rated, non-flammable HFC basedrefrigerant with a GWP of 733. Like R-32, R-466A provides a refrigerant with amuch lower GWP than HFC refrigerants currently in use, but not really low. Itsbig advantage over R32 is that it is non-flammable. R466A achieves this byusing a mix of 49% R32, 11.5% R125, and 39.5% R1311. R32 and R125 are the twocomponents found in R410A. R1311 has been previously used as a fire suppressant.This blend performs similarly to R410A, making adoption relatively easy.
Here is a link to more information on R466A.
HFOs
Hydrofluoroolefins (HFOs) are a special type of HFC. Theyhave at least one carbon double bond, making them less chemically stable than a“normal” HFC which has all single bonds. Because they are less chemicallystable, they do not persist in the atmosphere for long, and this reduces theirglobal warming potential. For example, HFO1233zd has a GWP of 0. HFO1233zd is alow pressure refrigerant for chiller applications. It has an A1 safety ratingand does not deplete the ozone. HFO1234yf has a GWP less than 1. It has an A2Lsafety rating – meaning that it is somewhat flammable. HFO1234yf is used inauto air conditioning systems. It has been what most auto manufacturers now useinstead of HFC134a. Here is a link to more information on HFOs.
Lower GWP refrigerants are the future of HVACR. Some old andsome new. Understanding how to safely work with these lower GWP refrigerantswill be an important part of all technician’s knowledge set going forward.